Publication: Organometallics

First reported Sep 20 2014 - Updated Sep 20 2014 - 1 reports

From Unsymmetrically Substituted Benzamidinato and Guanidinato Dichlorohydridosilanes to Novel Hydrido N-Heterocyclic Silylene Iron Complexes

Organometallics DOI: 10.1021/om5 ... [Published Organometallics - Sep 20 2014]
First reported Sep 08 2014 - Updated Sep 08 2014 - 1 reports

Insights into the Stability and Structures of Phosphine-Boranes and Their α-Metalated Derivatives

Organometallics DOI: 10.1021/om5 ... [Published Organometallics - Sep 08 2014]
First reported Sep 08 2014 - Updated Sep 08 2014 - 1 reports

Theoretical Studies on the Mechanism of Iridium-Catalyzed Alkene Hydrogenation by the Cationic Complex [IrH2(NCMe)3(PiPr3)]+

Organometallics DOI: 10.1021/om5 ... [Published Organometallics - Sep 08 2014]
Entities: Alkene, Hydrogenation
First reported Sep 05 2014 - Updated Sep 05 2014 - 1 reports

Formation of Hydroxyindenyl and Vinylidene Ligands by Reaction of Internal Alkynes with Cp*Fe(CO)(NCMe)Ph

† Department of Chemistry and ‡ Nanoscale Materials Characterization Facility, Materials Science and Engineering Department, University of Virginia , Charlottesville, Virginia 22904, United States Organometallics , Article ASAP DOI: 10.1021/om500748v ... [Published Organometallics - Sep 05 2014]
First reported Sep 05 2014 - Updated Sep 05 2014 - 1 reports

Macrocyclic Salen–Bis-NHC Hybrid Ligands and Their Application to the Synthesis of Enantiopure Bi- and Trimetallic Complexes

Salen and NHC ligands are among the most important ligands for homogeneous catalysis. We have recently reported bimetallic complexes, in which both motifs have been merged for the first time. However, the intermetallic distances, which play a crucial ... [Published Organometallics - Sep 05 2014]
First reported Sep 04 2014 - Updated Sep 04 2014 - 1 reports

Haptotropic Shift of [5]Cumulenes in Zirconocene Complexes and Effects of Steric Factors

Zirconium complexes of some [5]cumulene derivatives were studied for their variable coordination modes and haptotropic shifts. Some [5]cumulene compounds reacted with zirconocene(II) species to afford 1-zirconacyclopent-3-yne complexes that have five-membered ... [Published Organometallics - Sep 04 2014]
First reported Aug 30 2014 - Updated Aug 30 2014 - 1 reports

C–H Activation of Methyltrioxorhenium by Pincer Iridium Hydride To Give Agile Ir–Re Bimetallic Compounds

C–H activation of the CH3 group on methyltrioxorhenium (MTO) by [PNPIrH2]+ (1) affords the bimetallic complex [PNP(H)Ir-μ(CH2)-μ(O)-Re(O)2]+ (2). Investigation of the mechanism revealed that C–H activation is the rate-determining step, and it is preceded ... [Published Organometallics - Aug 30 2014]
First reported Aug 29 2014 - Updated Aug 29 2014 - 1 reports

Photochemical Reaction of Diruthenium Tetrahydride-Bridged Complexes with Carbon Dioxide: Insertion of CO2 into a Ru–H Bond versus CO Double-Bond Cleavage

Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology , O-okayama, Meguro-ku, Tokyo, 152-8552 Japan Organometallics , Article ASAP DOI: 10.1021/om500615u Publication Date (Web): August 28, 2014 Copyright ... [Published Organometallics - Aug 29 2014]
First reported Aug 29 2014 - Updated Aug 29 2014 - 1 reports

Synthesis and Characterization of Molybdenum(0) and Tungsten(0) Complexes of Tetramethylthiourea: Single-Source Precursors for MoS2 and WS2

The molybdenum(0) and tungsten(0) carbonyl complexes, [M(CO)n(TMTU)6–n] (M = Mo and W; TMTU = tetramethylthiourea; n = 4 and 5), have been prepared by addition of TMTU to the appropriate carbonyl precursors. In the solid state, the compounds are monomeric ... [Published Organometallics - Aug 29 2014]
Entities: Molybdenum, Tungsten, Ligand
First reported Aug 29 2014 - Updated Aug 29 2014 - 1 reports

A Theoretical Study On Rh(I) Catalyzed Enantioselective Conjugate Addition Reactions of Fluoroalkylated Olefins

In this study, quantum mechanical calculations have been performed to elucidate the mechanism and enantioselectivity in rhodium-catalyzed 1,4-conjugate addition reaction of a series of aryl groups to electron-deficient 4,4,4-trifluoro-1-phenyl-2-buten-1-one ... [Published Organometallics - Aug 29 2014]
First reported Aug 28 2014 - Updated Aug 28 2014 - 1 reports

Telluroether to Telluroxide Conversion in the Coordination Sphere of a Metal: Oxidation-Induced Umpolung of a Te–Au Bond

While Ph2Te is oxidized into Ph2TeCl2 in the presence of (tht)AuCl (tht = tetrahydrothiophene), reaction of (o-(Ph2P)C6H4)2Te (LTeP2) with the same gold reagent affords the complex LTeP2AuCl (1). Upon reaction with Ph3P, this complex is converted into ... [Published Organometallics - Aug 28 2014]
Entities: Chloride, Ligand, Reagent
First reported Aug 28 2014 - Updated Aug 28 2014 - 1 reports

Exploring Oxidation of Half-Sandwich Rhodium Complexes: Oxygen Atom Insertion into the Rhodium–Carbon Bond of κ2-Coordinated 2-Phenylpyridine

The reactions of oxygen atom transfer reagents with Rh(Cp*) complexes, each with a bidentate ligand and an accessible coordination site, are described (Cp* = η5-pentamethylcyclopentadienyl). When [Rh(Cp*)(phpy)(NCArF)][B(ArF)4] (1, phpy = 2-phenylene-κC1′-pyridine-κN, ... [Published Organometallics - Aug 28 2014]
Entities: Rhodium, Ligand, Oxygen

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From Unsymmetrically Substituted Benzamidinato ... [Published Organometallics - Sep 20 2014]
Theoretical Studies on the Mechanism of Iridium... [Published Organometallics - Sep 08 2014]
Insights into the Stability and Structures of P... [Published Organometallics - Sep 08 2014]
Macrocyclic Salen–Bis-NHC Hybrid Ligands and T... [Published Organometallics - Sep 05 2014]
Formation of Hydroxyindenyl and Vinylidene Liga... [Published Organometallics - Sep 05 2014]
Haptotropic Shift of [5]Cumulenes in Zirconocen... [Published Organometallics - Sep 04 2014]
C–H Activation of Methyltrioxorhenium by Pincer... [Published Organometallics - Aug 30 2014]
A Theoretical Study On Rh(I) Catalyzed Enantios... [Published Organometallics - Aug 29 2014]
Synthesis and Characterization of Molybdenum(0)... [Published Organometallics - Aug 29 2014]
Photochemical Reaction of Diruthenium Tetrahydr... [Published Organometallics - Aug 29 2014]
Telluroether to Telluroxide Conversion in the C... [Published Organometallics - Aug 28 2014]
Exploring Oxidation of Half-Sandwich Rhodium Co... [Published Organometallics - Aug 28 2014]
Donor Decomposition by Lewis Acids in Ziegler–N... [Published Organometallics - Aug 26 2014]
Reactivity of Organogold Compounds with B(C6F5)... [Published Organometallics - Aug 26 2014]
Template Synthesis of Tetracarbene Platinum(II)... [Published Organometallics - Aug 26 2014]
Distortional Effects of Noncovalent Interaction... [Published Organometallics - Aug 23 2014]
Mono- and Dimetalation of a Tridentate Bisimida... [Published Organometallics - Aug 22 2014]
Dinickelametallocenes: Sandwich Compounds of th... [Published Organometallics - Aug 21 2014]
Chromium-Catalyzed CO2–Epoxide Copolymerization [Published Organometallics - Aug 21 2014]
Tridentate Complexes of Group 10 Bearing Bis-Ar... [Published Organometallics - Aug 20 2014]
(Pyrazol-1-yl)carbonyl and Ester-Functionalized... [Published Organometallics - Aug 20 2014]
Catalytic C–F Bond Hydrogenolysis of Fluoroarom... [Published Organometallics - Aug 20 2014]
Synthesis and Evaluation of a Carbosilane Conge... [Published Organometallics - Aug 19 2014]
Experimental Study of the Mechanism of the Pall... [Published Organometallics - Aug 15 2014]
Anion-Dependent Switch in C–X Reductive Elimina... [Published Organometallics - Aug 15 2014]
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